The Bench is where your other Pokmon stay until your active Pokmon gets knocked out or you swap places yourself
The thing is that most lists are not obviously one way or the other
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You must pay a certain amount of ink for your character to be played, but you have to wait for the ink to dry (your next turn) before you can use their abilities (unless the card specifies differently.) Use a character ability that doesnt require them to exert
How To Legit Check Pokemon Cards When buying Pokemon cards, you should always legit check them
Every Legendary Pokmon will be up for grabs too