If you have to put Gothorita into play, I would recommend using Psybeam for sure the first turn so you can for sure do some damage and confuse the defending Pokemon, then depending on how lucky you're feeling would determine if you would use Double Slap which has the potential to do 40 damage, or Psybeam which does 20 damage every turn the next turn
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The Tyrant forces your opponents to pay three extra mana for every creature attacking you
Then pile on seconds with instants and sorceries like Arachnogenesis, Collective Unconscious, or Second Harvest and overwhelm the table
The necessity of casting it for its escape cost if you want it to remain on the battlefield can make it a hazard in EDH if you somewhat depend on your graveyard, but its a risk worth taking